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JOURNALS // Nanosystems: Physics, Chemistry, Mathematics // Archive

Nanosystems: Physics, Chemistry, Mathematics, 2016 Volume 7, Issue 6, Pages 983–1001 (Mi nano303)

This article is cited in 4 papers

PHYSICS

Silicene is a phantom material

E. F. Sheka

Department of Theoretical Physics and Mechanics Peoples’ Friendship University of Russia, Str. Miklukho-Maklay, 6, Moscow 117198, Russia

Abstract: The paper presents a comparative consideration of $sp^2$ nanocarbons and their silicon and higher tetrels analogues from the viewpoint of the spin molecular theory taking into account the electron correlation in open-shell molecules. High radicalization of silicene and quantum instability of flat honeycomb 2D structures of germanene and stanene make all the species phantom materials leaving graphene the only one-atom thick 2D solid free of the crucial restrictions.

Keywords: silicene, siligraphene, boronitrosilicene, spin molecular theory, unrestricted Hartree-Fock formalism, open-shell molecules.

Received: 30.05.2016

Language: English

DOI: 10.17586/2220-8054-2016-7-6-983-1001



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