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JOURNALS // Nanosystems: Physics, Chemistry, Mathematics // Archive

Nanosystems: Physics, Chemistry, Mathematics, 2018 Volume 9, Issue 4, Pages 468–472 (Mi nano331)

This article is cited in 5 papers

PHYSICS

Heat-treated nano-structured shungite rocks and electrophysical properties associated

S. V. Kovalevskiia, I. A. Moshnikovb, V. V. Kovalevskiia

a “Shungiton” Ltd Company, Petrozavodsk, Russia
b Institute of Geology, Karelian Research Center, RAS, Petrozavodsk, Russia

Abstract: Shungite rocks of two different types were treated at $\sim$ 1400$^\circ$C and a set of nanomaterials have been obtained. Among the different materials obtained were: carbon hollow fibers; spherical or ellipsoid particles; silicon carbide amorphous; crystalline nanofibers and nanoparticles having different morphologies; iron and iron silicide nanoparticles encapsulated into carbon shells. Measurements were performed for shielding effectiveness (SE) and the electrical conductivity ($\sigma$) of untreated and heat-treated shungite rocks. The shungite rock with dominated hyperfullerene carbon is remarkable for a two-fold increase in the $\sigma$ and a 10 dB increase in SE with a slight decrease of the carbon content by 1.5% in relation to the untreated sample. In contrast, the treated shungite rock with high SiC nanofiber content is characterized by a halving of the $\sigma$ and a 10 dB decrease in SE with a decrease of the carbon content by 6% relative to the original sample.

Keywords: shungite rocks, carbon, carbon nano-sized shells and fibers, SiC nano-sized fibers, shielding effectiveness, electrical conductivity.

PACS: 68.37.Og, 61.48.-c

Received: 06.03.2018
Revised: 13.06.2018

Language: English

DOI: 10.17586/2220-8054-2018-9-4-468-472



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