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JOURNALS // Nanosystems: Physics, Chemistry, Mathematics // Archive

Nanosystems: Physics, Chemistry, Mathematics, 2012 Volume 3, Issue 4, Pages 75–81 (Mi nano696)

CHEMISTRY

Features of phase formation in the ZrO$_2$–TiO$_2$ system under hydrothermal conditions

A. K. Vasilevskaya, O. V. Almjasheva

State Technological Institute of St. Petersburg (Technical University)

Abstract: Influence of chemical prehistory of the precursors on chemical reactions in the ZrO$_2$, TiO$_2$ system under hydrothermal conditions was investigated. The possibility of formation phases with fluorite-like structure (Zr,Ti)$_2$O$_4$ at temperature 240$^\circ$C is shown, it being process of nucleation on stage of coprecipitation of hydroxides is crucial.

Keywords: nanoparticles, nanocomposites, structural transformations, ZrO$_2$, TiO$_2$, hydrothermal synthesis.



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