S. A. Lermontov, A. N. Malkova, L. L. Yurkova, V. P. Kazachenko, V. K. Ivanov, A. Y. Baranchikov, Yu. D. Tret'yakov, “Sulfated alumina in the oligomerization reaction of hexene-1 and cyclohexene”, Nanosystems: Physics, Chemistry, Mathematics, 2013, Volume 4, Issue 1,Pages <nobr>113

Sulfated alumina in the oligomerization reaction of hexene-1 and cyclohexene

S. A. Lermontov^a, A. N. Malkova^a, L. L. Yurkova^a, V. P. Kazachenko^a, V. K. Ivanov^bc, A. Y. Baranchikov^b, Yu. D. Tret'yakov^c

^a Institute of Physiologically Active Compounds RAS, Chernogolovka
^b Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow
^c Lomonosov Moscow State University, Faculty of Materials Science

Abstract: Reactions of hexene-1 and cyclohexene oligomerization were studied over solid superacid catalyst sprepared by impregnation or by washing of alumina by sulfate-containing compounds (sulfuric acid or salts). А 100% conversion of hexene-1 was achieved for all investigated catalysts at room temperature. The maximum conversion of cyclohexene was 25% at 83$^\circ$C.

Keywords: solid superacids, sulfated metal oxides, oligomerization of olefins, hexene-1, cyclohexene.

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