S. A. Lermontov, A. N. Malkova, L. L. Yurkova, A. Y. Baranchikov, V. K. Ivanov, “Sulfated nano-ceria as a catalyst of hex-1-ene oligomerization”, Nanosystems: Physics, Chemistry, Mathematics, 2013, Volume 4, Issue 5,Pages <nobr>690

Sulfated nano-ceria as a catalyst of hex-1-ene oligomerization

S. A. Lermontov^a, A. N. Malkova^a, L. L. Yurkova^a, A. Y. Baranchikov^b, V. K. Ivanov^bc

^a Institute of Physiologically Active Compounds of the Russian Academy of Sciences, Chernogolovka, Moscow region, Russia
^b Kurnakov Institute of General and Inorganic Chemistry of Russian Academy of Sciences, Moscow, Russia
^c Materials Science Department, Moscow State University, Moscow, Russia

Abstract: Oligomerization of hex-1-ene over acid catalysts obtained by the impregnation of cerium dioxide by sulfatecontaining compounds (sulfuric acid or its salts) was studied. Maximum conversion of hexene-1 over sulfated ceria catalysts was 7–12% at 60$^\circ$C.

Keywords: sulfated ceria, olefins oligomerization, hex-1-ene.

PACS: 82.65.+r, 81.07.Bc, 81.16.Be

Language: English