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JOURNALS // Nanosystems: Physics, Chemistry, Mathematics // Archive

Nanosystems: Physics, Chemistry, Mathematics, 2013 Volume 4, Issue 6, Pages 834–843 (Mi nano822)

The effect of fullerene C$_{60}$ on the mechanical and dielectrical behavior of epoxy resins at low loading

D. V. Pikhurova, V. V. Zuevab

a National Research University of Information Technologies, Mechanics and Optics, 49 Kronverkskiy pr., 197101 Saint Petersburg, Russian Federation
b Institute of Macromolecular Compounds of the Russian Academy of Sciences, 31 Bolshoi pr., 199004 Saint Petersburg, Russian Federation

Abstract: Fullerene C$_{60}$ / epoxy polymers nanocomposites with different C$_{60}$ loadings (0.01–0.12 wt. %) have been prepared. Mechanical testing shows that compared with the neat epoxy, the mechanical and toughening properties of the composites are greatly improved. The addition of fullerene C$_{60}$ increased the modulus of the epoxy (up to 20 %), but the glass transition temperature was unaffected. The measured impact strength was also increased, from 38 to 115 kJ/m$^{2}$ with the addition of 0.12 wt.% of fullerene C$_{60}$. The toughening mechanism has been discussed. Dielectric spectroscopy was used to investigate the influence of nanoparticles on the relaxation processes in the polymer matrix.

Keywords: epoxy resins, dielectric spectroscopy, relaxation processes, fullerene C$_{60}$, nanocomposites, mechanical properties.

PACS: 81.07.Lb

Language: English



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