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JOURNALS // Nanosystems: Physics, Chemistry, Mathematics // Archive

Nanosystems: Physics, Chemistry, Mathematics, 2014 Volume 5, Issue 5, Pages 709–717 (Mi nano901)

Concentration dependence of electric conductivity and ph for aqueous solutions of watersoluble light fullerene – C$_{60}$ [= C(COOH)$_{2}$]$_{3}$ trismalonate

K. N. Semenova, N. A. Charykovbc, A. S. Kritchenkova, I. A. Cherepkovab, O. S. Manyakinab, D. P. Tyurinb, A. A. Shestopalovab, V. A. Keskinovb, E. A. Kulenovad, K. V. Ivanovab, N. M. Ivanovaa, D. G. Letenkoe, V. A. Nikitinf, E. L. Fokinaa

a St. Petersburg State University, Saint-Petersburg, Russia
b St. Petersburg State Technological Institute (Technical University), Saint-Petersburg, Russia
c St. Petersburg State Electro-Technical University (LETI), Saint-Petersburg, Russia
d D. Serikbayev East-Kazakhstan state technical university, Ust-Kamenogorsk, Kazakhstan
e St. Petersburg State University Architecture Academy, Saint-Petersburg, Russia
f St. Petersburg State Technical University, Saint-Petersburg, Russia

Abstract: Studies of the concentration dependence of electric conductivity and pH for aqueous solutions of the light fullerene – C$_{60}$ [= C(COOH)$_{2}$]$_{3}$ trismalonate were performed at 25$^\circ$C. From both data (from the equivalent electric conductivity and pH), the apparent degree of dissociation and concentration dissociation constants of C$_{60}$ [= C(COOH)$_{2}$]$_{3}$ in aqueous solutions were calculated. Thermodynamic dissociation constants of C$_{60}$ [= C(COOH)$_{2}$]$_{3}$ in aqueous solutions, calculated for infinitely dilute solutions by the both methods, were reasonably similar.

Keywords: tris-malonate of light fullerene, electric conductivity.

PACS: 61.48.+c

Received: 20.03.2014

Language: English



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