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JOURNALS // Optics and Spectroscopy // Archive

Optics and Spectroscopy, 2021 Volume 129, Issue 12, Page 1483 (Mi os1119)

This article is cited in 2 papers

Spectroscopy and physics of atoms and molecules

Dipole-dipole polarizability of the cadmium $^1$S$_0$ state revisited

Uwe Hohm

Technische Universität Braunschweig, Institut fur Physikalische und Theoretische Chemie, Braunschweig, Germany

Abstract: Experimental results and high-level quantum chemical ab initio calculations of the static polarizability $\alpha = \alpha(\omega = 0)$ of the cadmium $^1$S$_0$ state are still in marked disagreement. Here we analyze this discrepancy by using experimentally determined dipole oscillator strength distributions (DOSD). It will be shown that within this procedure the experimentally determined static polarizability $\alpha_0$ will shift from 49.7 $\pm$ 1.6 au to considerably lower values. We now conclude an experimentally determined polarizability of $\alpha_0$ = 47.5 $\pm$ 2.0 au in much better agreement with the latest calculations of $\alpha_0\approx$ 46 au.

Keywords: cadmium, polarizability, DOSD.

Received: 23.06.2021
Revised: 03.08.2021
Accepted: 03.08.2021

Language: English


 English version:
Optics and Spectroscopy, 2022, 130:4, 290–294


© Steklov Math. Inst. of RAS, 2024