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Optics and Spectroscopy, 2021 Volume 129, Issue 5, Pages 614–617 (Mi os136)

Spectroscopy of condensed matter

Luminescent properties of boron difluoride enaminedibenzoylmethanates and their oxygen analogues

A. G. Mirochnika, G. O. Tretyakovaab, E. V. Fedorenkoa, N. D. Podlozhnyukb

a Institute of Chemistry, Far East Branch of the Russian Academy of Sciences, Vladivostok
b Far Eastern Federal University, Vladivostok

Abstract: The luminescent properties of boron difluoride enaminedibenzoylmethanates and their oxygen analogues in solutions and crystals were investigated. During the transition from dilute solutions to concentrated solutions and crystals, a significant bathochromic shift in the maxima of the luminescence and excitation spectra is observed. It is established that the luminescence of crystals and concentrated solutions has an excimer nature.

Keywords: boron difluoride complexes, luminescence, excimers.

Received: 21.04.2020
Revised: 24.11.2020
Accepted: 10.01.2021

DOI: 10.21883/OS.2021.05.50886.136-20


 English version:
Optics and Spectroscopy, 2021, 129:6, 670–673

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© Steklov Math. Inst. of RAS, 2024