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Optics and Spectroscopy, 2021 Volume 129, Issue 5, Pages 642–649 (Mi os140)

This article is cited in 3 papers

Optical materials

Synthesis and investigation of the structure and properties of photoactive ZnO–SnO$_2$–Ag(AgCl) nanomaterials for medicine and environmental applications

V. M. Volynkina, D. P. Danilovichb, S. K. Evstropievabc, K. V. Dukelskiiadc, K. Yu. Senchike, R. V. Sadovnichiia, V. M. Kiseleva, I. V. Bagrova, A. S. Saratovskiibf, N. V. Nikonorovc, P. V. Bezborodkina

a S. I. Vavilov State Optical Institute", St. Petersburg
b State Technological Institute of St. Petersburg (Technical University)
c St. Petersburg National Research University of Information Technologies, Mechanics and Optics
d St. Petersburg State University of Telecommunications
e N. N. Petrov Research Institute of Oncology, Saint-Petersburg, Pesochny
f I. V. Grebenshchikov Institute of Silicate Chemistry of the Russian Academy of Sciences, St. Petersburg

Abstract: Photoactive ZnO–SnO$_2$–Ag(AgCl) nanomaterials have been prepared by polymer-salt method. Prepared materials able to generate singlet oxygen under UV and blue light irradiation. Materials structure and properties have been studied by optical and luminescence spectroscopy, XRD and SEM analysis. It was found that the structure of ZnO–SnO$_2$–Ag(AgCl) materials consists of hexagonal ZnO, tetragonal SnO$_2$, Ag and AgCl crystals having size 50–60 nm. Obtained materials able to generate chemically active singlet oxygen under UV irradiation and have high bactericidal properties against both gram-positive and gram-negative bacteria. The increase of Ag content enhances the bactericidal properties of prepared materials.

Keywords: luminescence, ZnO, crystal, singlet oxygen.

Received: 15.01.2021
Revised: 15.01.2021
Accepted: 05.02.2021

DOI: 10.21883/OS.2021.05.50892.1819-21


 English version:
Optics and Spectroscopy, 2021, 129:7, 746–753

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© Steklov Math. Inst. of RAS, 2024