Optics and Spectroscopy, 2022 Volume 130, Issue 1,Pages 28–32(Mi os1636)
Materials of the International Seminar of the Institute of Spectroscopy of the Russian Academy of Sciences (ISAN), dedicated to the anniversary of Professor M.N. Popova Spectroscopy of condensed state
Wide-band EPR spectroscopy of SrY$_2$O$_4$:Ho$^{3+}$ crystal
Abstract:
EPR spectra of impurity Но$^{3+}$ ions in oriented SrY$_2$O$_4$ single-crystals are registered at the temperature 4.2 K in the frequency range from 70 to 180 GHz. The results of measurements evidence for the substitution of Но$^{3+}$ ions for the Y$^{3+}$ ions at the structurally nonequivalent sites $R1$ and $R2$ with the local $C_s$ point symmetry. The values of $g$-factors, hyperfine structure constants and the energy gaps berween the ground and the first excited non-degenherate crystal-field sublevels of the ground $^5I_8$ multiplet are determined. The observed specific features of the ground states of Но$^{3+}$ ions (non-Kramers doublets with the zero-field splittings of 4.30 and 1.67 cm$^{-1}$) open a possibility to identify transitions in optical spectra of SrY$_2$O$_4$ : Ho and inelastic neutron scattering spectra of SrHo$_2$O$_4$ crystals.