Optics and Spectroscopy, 2022 Volume 130, Issue 1,Pages 104–110(Mi os1646)
Materials of the International Seminar of the Institute of Spectroscopy of the Russian Academy of Sciences (ISAN), dedicated to the anniversary of Professor M.N. Popova Spectroscopy of condensed state
Study of the magnetic properties of neodymium and samarium iron borates by the method of erbium spectroscopic probe
Abstract:
Iron borates NdFe$_3$(BO$_3$)$_4$ and SmFe$_3$(BO$_3$)$_4$ activated with 1% erbium, with a huntite structure (space symmetry group $R$32) were investigated by the method of erbium spectroscopic probe. From an analysis of the temperature dependence of the transmission spectra in the region of the $^4I_{15/2}$$\to$$^4I_{13/2}$ transition in the Er$^{3+}$ ion, it was found that both studied compounds order antiferromagnetically at $T_{\mathrm{N}}\approx$ 33 K into an easy-plane magnetic structure. No other phase transitions were found.
Keywords:multiferroics, optical spectroscopy, crystals with rare earths, Kramers ions.