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JOURNALS // Optics and Spectroscopy // Archive

Optics and Spectroscopy, 2022 Volume 130, Issue 6, Pages 832–837 (Mi os1761)

Proceedings of The XXV Annual International Conference "Saratov Fall Meeting 2021", September 27-October 1, 2021, Saratov, Russia
Nanophotonics

Effect of chitosan on the orientation micellar ordering of pluronic F-127 gel phase in an aqueous medium

N. O. Gegel', V. N. Kharlamov, A. B. Shipovskaya

Saratov State University

Abstract: The effect of chitosan on the orientational micellar association of Pluronic F-127 in an aqueous medium in the range of 4–37$^\circ$Ñ was studied by polarization microscopy and rotational viscometry. It has been established that this amphiphilic copolymer undergoes a phase transition with increasing temperature into a shape-stable hydrogel characterized by optical dichroism and viscosity rheograms with a yield point. The addition of chitosan suppresses the effect of optical anisotropy, affects the gelation time and viscoelastic characteristics of a binary mixture with the implementation of flow curves of dilatant liquids or structured compositions with different levels of micellar ordering. A correlation has been found between the optical texture of the macroscopic gel phase of Pluronic F-127, its mixtures with chitosan, and the viscoelastic properties of the polymer system.

Keywords: pluronic F127, chitosan, sol-gel transition, micellar phase, orientational ordering.

Received: 23.12.2021
Revised: 21.01.2022
Accepted: 22.03.2022

DOI: 10.21883/OS.2022.06.52623.25-22



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© Steklov Math. Inst. of RAS, 2025