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JOURNALS // Optics and Spectroscopy // Archive

Optics and Spectroscopy, 2022 Volume 130, Issue 8, Pages 1160–1163 (Mi os1801)

Spectroscopy and physics of atoms and molecules

Determination of vibrational parameters of $^{76}$GeH$_4$ from precision experimental data

A. L. Fomchenko, E. S. Bekhtereva, O. V. Gromova, N. I. Nikolaeva

Research School of High-Energy Physics, Tomsk Polytechnic University, 634050 Tomsk, Russia

Abstract: Harmonic frequencies, anharmonic parameters, and tetrahedral splitting parameters have been determined for the $^{76}$GeH$_4$ molecule, based on experimental data of band centers. As a result, the set of 3 harmonic frequencies, 8 anharmonic parameters, and 8 tetrahedral splitting parameters reproduces 31 initial experimental band centers with a root mean square deviation 0.054 cm$^{-1}$.

Keywords: GeH$_4$, vibrational parameters, local mode model.

Received: 27.04.2022
Revised: 27.04.2022
Accepted: 26.05.2022

DOI: 10.21883/OS.2022.08.52900.3612-22



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© Steklov Math. Inst. of RAS, 2025