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JOURNALS // Optics and Spectroscopy // Archive

Optics and Spectroscopy, 2022 Volume 130, Issue 12, Pages 1922–1929 (Mi os1906)

Nanophotonics

Electron spin resonance of NV$^{(-)}$-centers in synthetic fluorescent diamond microcrystals under conditions of optical spin polarization

V. Yu. Osipova, K. V. Bogdanovb, A. Rampersaudc, K. Takaid, Ya. Ishiguroe, A. V. Baranovb

a Ioffe Institute, 194021 St. Petersburg, Russia
b ITMO University, 197101 St. Petersburg, Russia
c Columbus Nanoworks Ltd., Columbus, 43212 Ohio, United States
d Department of Chemical Science and Technology, Hosei University, Koganei, 184-8584 Tokyo, Japan
e Department of Electrical and Electronic Engineering, Tokyo Denki University, 120-8551 Tokyo, Japan

Abstract: Electron paramagnetic resonance (EPR) spectra of synthetic diamond microcrystals with NV$^{(-)}$-centers have been studied. It is shown that under the conditions of irradiation of the material with the light of a xenon lamp at low temperatures $\sim$ 100 K, the intensities of the EPR signals corresponding to the “forbidden” ($\Delta m_s$ = 2) and low field allowed ($\Delta m_s$ = 1) transitions are amplified several times, while the EPR signals from paramagnetic nitrogen and impurity nickel in the charge state -1 practically do not change. This is due to a change in the population of levels of the ground triplet state of the NV$^{(-)}$-center and the optical polarization of spins in the state $m_s$ = 0 of the triplet level.

Keywords: nitrogen-vacancy centers, synthetic diamond, electron paramagnetic resonance, spin polarization, luminescence.

Received: 25.10.2022
Revised: 15.11.2022
Accepted: 15.11.2022

DOI: 10.21883/OS.2022.12.54101.4248-22



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© Steklov Math. Inst. of RAS, 2025