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Optics and Spectroscopy, 2025 Volume 133, Issue 7, Pages 734–740 (Mi os1947)

Optical materials

Refractive index dispersion and Raman scattering spectra of a germanium single crystal enriched with $^{70}$Ge isotope

T. V. Koterevaa, V. A. Gavvaa, V. A. Lipskya, A. V. Nezhdanovb, Yu. S. Belozerova, A. D. Bulanovab, V. G. Plotnichenkoc

a Institute of Chemistry of High-Purity Substances RAS, Nizhnii Novgorod
b Lobachevsky State University of Nizhny Novgorod
c Fiber Optics Research Center of the Russian Academy of Sciences

Abstract: The spectral dependence of the refractive index (RI) of a germanium single crystal enriched in the isotope $^{70}$Ge ($>$ 99.92 at.%) in the spectral range 5500–500 cm$^{-1}$ (1.8–20 $\mu$m) was measured. The data obtained are compared with the results for single crystals of other germanium isotopes ($^{72}$Ge, $^{73}$Ge, $^{74}$Ge, $^{76}$Ge). In the entire studied range, the refractive index values of $^{70}$Ge are higher than for heavier isotopes. This confirms the previously identified trend towards an increase in the RI with a decrease in the atomic mass of germanium isotopes. The Raman spectra of first- and second-order light scattering of a $^{70}$Ge single crystal at a temperature of 293 K.

Keywords: elementary semiconductors, isotopic effects, interference refractometry, refractive index, Raman spectroscopy.

Received: 07.03.2025
Revised: 22.04.2025
Accepted: 23.04.2025

DOI: 10.61011/OS.2025.07.61105.7671-25



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© Steklov Math. Inst. of RAS, 2025