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Optics and Spectroscopy, 2021 Volume 129, Issue 11, Pages 1339–1359 (Mi os22)

This article is cited in 1 paper

Spectroscopy and physics of atoms and molecules

Asymptotically spin forbidden quasimolecular radiative transitions

A. Z. Devdariani

Saint Petersburg State University

Abstract: Theoretical works on radiative transitions produced in thermal collisions of atoms of groups 2À, 12 of the periodic table with atoms of inert gases in the normal state as well as in nonsymmetrical collisions of inert gas atoms are discussed in the review. Such collisions are accompanied by either the decay or the population of the lower metastable state $^{3}P_{2}$. The discussion has been carried out within the framework of analytical approaches based on the Fermi pseudopotential method and semiempirical method. The results on rate constants, absorption coefficients, radiative lifetimes, spectral profiles have been presented.

Keywords: optical collision spectroscopy, quasimolecular state interaction, Fermi pseudopotential, semi empirical procedure of term reconstruction.

Received: 04.08.2021
Revised: 04.08.2021
Accepted: 10.08.2021

DOI: 10.21883/OS.2021.11.51632.2609-21


 English version:
Optics and Spectroscopy, 2022, 130:14, 2062–2081

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© Steklov Math. Inst. of RAS, 2025