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JOURNALS // Optics and Spectroscopy // Archive

Optics and Spectroscopy, 2020 Volume 128, Issue 11, Pages 1614–1620 (Mi os246)

This article is cited in 2 papers

Spectroscopy of condensed matter

Solution of the inverse problem for the vibronic analogue of the complex Fermi resonance based on the plane Jacobi rotations

V. A. Kuzmitsky

University of Civil Protection of the Republic of Belarus, Minsk, Belarus

Abstract: Based on algebraic methods, an exact solution is found to the inverse problem for a complex vibronic analogue of the Fermi resonance, which consists in determining from the spectral data for the observed conglomerate of lines (energies $E_k$ and transition intensities $I_k$, $k = 1,2, \dots,n$; $n>$ 2) the energies of the dark states, $A_m$, and the matrix elements $B_m$ of their coupling with the bright state. In the first part of the algorithm, using plane Jacobi rotations, an orthogonal similarity transformation matrix $X$ is found, the first row of which is subject to the condition $(X_{1k})^2=I_{k}$ on its elements, since only one unperturbed state is bright. In the second part, the quantities $A_m$ and $B_m$ are obtained from the solution of the eigenvalue problem for the block of dark states of the matrix $X\operatorname{diag}(\{E_k\})X^{-1}$.

Keywords: vibronic interaction, complex vibronic analogue of the Fermi resonance, inverse problem, plane Jacobi rotations.

Received: 10.01.2020
Revised: 25.06.2020
Accepted: 28.07.2020

DOI: 10.21883/OS.2020.11.50163.3-20


 English version:
Optics and Spectroscopy, 2020, 128:11, 1744–1751

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© Steklov Math. Inst. of RAS, 2025