Abstract:
Based on algebraic methods, an exact solution is found to the inverse problem for a complex vibronic analogue of the Fermi resonance, which consists in determining from the spectral data for the observed conglomerate of lines (energies $E_k$ and transition intensities $I_k$, $k = 1,2, \dots,n$; $n>$ 2) the energies of the dark states, $A_m$, and the matrix elements $B_m$ of their coupling with the bright state. In the first part of the algorithm, using plane Jacobi rotations, an orthogonal similarity transformation matrix $X$ is found, the first row of which is subject to the condition $(X_{1k})^2=I_{k}$ on its elements, since only one unperturbed state is bright. In the second part, the quantities $A_m$ and $B_m$ are obtained from the solution of the eigenvalue problem for the block of dark states of the matrix $X\operatorname{diag}(\{E_k\})X^{-1}$.
Keywords:vibronic interaction, complex vibronic analogue of the Fermi resonance, inverse problem, plane Jacobi rotations.