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Optics and Spectroscopy, 2020 Volume 128, Issue 1, Pages 63–67 (Mi os496)

This article is cited in 3 papers

Spectroscopy of condensed matter

Spectral-luminescent and lasing properties of merocyanine dye solutions in presence of silver nanoparticles

D. A. Afanasyevab, N. Kh. Ibrayevb, G. S. Omarovab, A. V. Kulinichc, A. A. Ishchenkoc

a Institute of Applied Mathematics, Karaganda, Republic of Kazakhstan
b Institute of Molecular Nanophotonics, Buketov Karaganda State University, Karaganda, Republic of Kazakhstan
c Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kyiv

Abstract: The effect of silver nanoparticles (NPs) on the spectral-luminescence and lasing properties of an ethanolic solution of positive solvatochromic merocyanine dye is studied. Increases in the absorption cross section, intensity, and duration of dye fluorescence are observed upon the addition of NPs to the solution. This leads to a decrease in the merocyanine lasing threshold. As a result, laser generation can be obtained in the presence of silver NPs ($C_{\mathrm{Ag}}$ = 10$^{-12}$ mol/L) at a dye concentration (10$^{-4}$ mol/L) at which it cannot be achieved in the absence of NPs. It is noteworthy that the power density of laser pumping in the former case is lower than in the latter case.

Keywords: merocyanine dye, silver nanoparticles, plasmon effect, absorption and fluorescence intensity, stimulated emission.

Received: 21.09.2019
Revised: 21.09.2019
Accepted: 01.10.2019

DOI: 10.21883/OS.2020.01.48839.270-19


 English version:
Optics and Spectroscopy, 2020, 128:1, 61–65

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