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JOURNALS // Optics and Spectroscopy // Archive

Optics and Spectroscopy, 2019 Volume 127, Issue 5, Pages 730–735 (Mi os543)

Spectroscopy and physics of atoms and molecules

Physically correct configuration spaces in the description of the internal dynamics of a rigid molecule

A. V. Burenin

Institute of Applied Physics of the Russian Academy of Sciences, 603950, Nizhny Novgorod, Russia

Abstract: A family of configuration spaces in the description of the internal dynamics of a rigid molecule has been considered. It has been shown that the requirement of the physical correctness of the description leads to serious restrictions for such spaces. In particular, only spaces satisfying the Eckart condition are allowed for a nonlinear rigid molecule.

Keywords: vibration, rotation, Eckart–Sayvetz conditions.

Received: 18.04.2019
Revised: 03.07.3019
Accepted: 08.07.2019

DOI: 10.21883/OS.2019.11.48506.144-19


 English version:
Optics and Spectroscopy, 2019, 127:5, 792–797

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