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JOURNALS // Optics and Spectroscopy // Archive

Optics and Spectroscopy, 2018 Volume 125, Issue 3, Pages 318–323 (Mi os903)

Spectroscopy and physics of atoms and molecules

On double-valued wave functions in the description of intramolecular coordinate motions

A. V. Burenin

Institute of Applied Physics, Russian Academy of Sciences, Nizhny Novgorod, 603950, Russia

Abstract: It is shown that the appearance of double-valued wave functions in constructing the discrete-spectrum classification of coordinate motions in molecules with a linear core and two identical tops using the CNPI-group methods is the consequence of a physically incorrect determination of the action of symmetry operations on variables of a configuration space of the molecule.

Received: 14.05.2018

DOI: 10.21883/OS.2018.09.46544.135-18


 English version:
Optics and Spectroscopy, 2018, 125:3, 331–336

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© Steklov Math. Inst. of RAS, 2025