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Optics and Spectroscopy, 2018 Volume 124, Issue 5, Pages 592–599 (Mi os995)

Spectroscopy of atoms and molecules

Certification of control gas mixtures using modern spectroscopy: an approach and application

L. A. Konopelkoab, V. V. Beloborodovab, D. V. Rumiantseva, D. N. Selukovc

a D. I. Mendeleev Institute for Metrology, St. Petersburg, 190005, Russia
b ITMO University, St. Petersburg, 197101, Russia
c OOO "MONITORING", St. Petersburg, 196247, Russia

Abstract: The possibility of using the available spectroscopic databases for high-precision measurements of spectral parameters of gases has been studied. A new approach to measuring concentrations of gaseous components (ÍCl, CO, NO, SO$_2$) in gas mixtures employing the HITRAN or GEISA spectroscopic databases has been proposed. A certification method of control gas mixtures using Fourier-transform IR spectroscopy has been developed to transfer the mole-fraction units to working standards in order to reduce the required number of reference standards and improve the accuracy of measurements.

Received: 15.12.2017

DOI: 10.21883/OS.2018.05.45937.289-17


 English version:
Optics and Spectroscopy, 2018, 124:5, 624–631

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