RUS  ENG
Full version
JOURNALS // Problemy Fiziki, Matematiki i Tekhniki (Problems of Physics, Mathematics and Technics) // Archive

PFMT, 2024 Issue 1(58), Pages 57–62 (Mi pfmt950)

PHYSICS

Degree of phase transformations under conditions of polythermal synthesis of strontium-substituted ferromolybdate

M. V. Yarmolicha, N. A. Kalandaa, A. V. Petrova, S. K. Lazarukb, A. V. Semchenkoc, D. Sangaad, S. Munkhtsetsege

a Scientific-Practical Materials Research Centre of the NAS of Belarus, Minsk
b Belarusian State University of Informatics and Radioelectronics, Minsk
c Francisk Skorina Gomel State University
d Institute of Physics and Technology of MAS, Ulanbaatar
e National University of Mongolia, Ulanbaatar

Abstract: The sequence of phase transformations during the crystallization of Sr$_{1,5}$La$_{0,5}$FeMoO$_{6-\delta}$ was investigated by the solid-phase reactions method. It has been established that in order to effectively minimize the influence of intermediate reaction products, it is advisable to use precursors and combined heating modes. As a result, it was possible to obtain the single-phase Sr$_{1,5}$La$_{0,5}$FeMoO$_{6-\delta}$ powder with the Curie temperature of $450$ K and a magnetization value of $40.9$ A$\cdot$m$^2\cdot$kg$^{-1}$ at $T = 77$ K in the magnetic field of $0.86$ T.

Keywords: lanthanum-strontium ferromolybdate solid solution, thermogravimetric analysis, X-ray phase analysis, crystallization rate, sequence and degree of phase transformations, magnetization.

UDC: 539.23; 537.311.3; 537.622

Received: 16.01.2024

DOI: 10.54341/20778708_2024_1_58_57



© Steklov Math. Inst. of RAS, 2024