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Fizika i Tekhnika Poluprovodnikov, 2022 Volume 56, Issue 2, Pages 156–160 (Mi phts6987)

XVII Interstate Conference ''Thermoelectrics and Their Applications -- 2021" (ISCTA 2021 St. Petersburg, September 13-16, 2021)

Block and single-crystal films of bismuth-antimony alloy 3–12 at.% with an underlayer of antimony

D. D. Efimova, V. A. Komarova, N. S. Kablukovab, E. V. Demidova, M. V. Staritsync

a Herzen State Pedagogical University of Russia, 191186 St. Petersburg, Russia
b St. Petersburg State University of Technology and Design, 191186 St. Petersburg, Russia
c Prometei Central Research Institute of Structural Materials, St. Petersburg

Abstract: The influence of an antimony sublayer (10 nm) on the structure and galvanomagnetic properties of thin films of a bismuth-antimony solid solution (3–12 at.% Sb) up to 1 $\mu$m thick has been studied. The films were produced on mica substrates by discrete vacuum evaporation and zone recrystallization. We found that the misorientation of the crystallite plane (111) increases relative to the film plane as well as the crystallite sizes decrease. The antimony underlayer does not change the crystallographic orientation during recrystallization and increases the film adhesion. The change in the galvanomagnetic coefficients when using a sublayer is due to the classical dimensional effect and increasing plane deformation.

Keywords: bismuth, antimony, thin film, antimony underlayer, single-crystal film, atomic force microscopy.

Received: 19.09.2021
Revised: 24.09.2021
Accepted: 24.09.2021

DOI: 10.21883/FTP.2022.02.51953.20a



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