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Pisma v Zhurnal Tekhnicheskoi Fiziki, 2021 Volume 47, Issue 12, Pages 23–26 (Mi pjtf4758)

This article is cited in 1 paper

Interaction of keV-energy $\alpha$-particles with glycyl僕eucine molecules

A. A. Basalaeva, A. G. Buzykinb, V. V. Kuz'micheva, M. N. Panova, A. V. Petrovc, O. V. Smirnova

a Ioffe Institute, St. Petersburg
b Peter the Great St. Petersburg Polytechnic University
c Institute of Chemistry, St. Petersburg State University

Abstract: Radiation-induced damage of isolated glycyl僕eucine (C$_{8}$H$_{16}$N$_{2}$O$_{3}$) molecules by the impact of He$^{2+}$ ions has been studied. Relative cross sections of the main processes of charged state variation in collision parties and relative cross sections of fragmentation for singly and doubly charged molecular ions formed due to single collisions between glycyl僕eucine molecules and He$^{2+}$ ions have been determined for the first time. Optimized geometry of the molecule and singly charged molecular ion of glycyl僕eucine has been calculated by method of density functional theory.

Keywords: electron capture, dipeptides, fragmentation, time-of-flight mass spectrometry.

Received: 26.02.2021
Revised: 26.02.2021
Accepted: 19.03.2021

DOI: 10.21883/PJTF.2021.12.51062.18746


 English version:
Technical Physics Letters, 2021, 47:8, 589–592

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© Steklov Math. Inst. of RAS, 2024