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Pisma v Zhurnal Tekhnicheskoi Fiziki, 2021 Volume 47, Issue 11, Pages 51–54 (Mi pjtf4779)

Impedance spectroscopy of charge conducting composite materials based on microfibers of polyvinylidene fluoride copolymer with trifluoroethylene modified with polypyrrole

V. M. Kapralovaa, I. Yu. Sapurinab, N. T. Sudara, A. A. Tretiakova, O. Gryshkovc, B. Glasmacherc

a Peter the Great St. Petersburg Polytechnic University
b Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg
c Institute for Multiphase Processes, Leibniz Universität Hannover, Garbsen, Germany

Abstract: The impedance spectra of composite nonwoven materials based on nano- and microfibers of polyvinylidene fluoride copolymer with trifluoroethylene modified with polypyrrole with various degrees of doping are studied in the frequency range 1 $\times$ 10$^{3}$ – 1.5 $\times$ 10$^{7}$ Hz. It is found that an increase in the degree of doping of the polypyrrole coating of nanofibers leads to a decrease in the imaginary and real components of the electrical impedance. Regardless of their size, the shape of the hodographs is close to the arc of a circle based on the axis of the real component, which allows considering the studied material as a nanocomposite polymer electrolyte, the dielectric characteristics of which can be reversibly changed.

Keywords: nonwoven materials, polypyrrole, polyvinylidene fluoride, impedance.

Received: 29.01.2021
Revised: 12.03.2021
Accepted: 15.03.2021

DOI: 10.21883/PJTF.2021.11.51010.18721


 English version:
Technical Physics Letters, 2021, 47:8, 561–564

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© Steklov Math. Inst. of RAS, 2024