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Pisma v Zhurnal Tekhnicheskoi Fiziki, 2018 Volume 44, Issue 13, Pages 36–43 (Mi pjtf5761)

This article is cited in 12 papers

Pulsed activation of a fuel cell on the basis of a proton-exchange polymer membrane

E. A. Galitskayaab, E. V. Gerasimovab, Yu. A. Dobrovolskyb, G. M. Donc, A. S. Afanas’evd, A. V. Levchenkob, A. V. Sivakc, V. V. Sinitsynab

a Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
b Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
c OOO Inenergy, Moscow, Russia
d Branch 46, Central Scientific Research Institute, Ministry of Defense of the Russian Federation, Mytishchi, Moscow oblast, Russia

Abstract: The influence of pulsed activation on the electrochemical characteristics of fuel cells based on the Nafion proton-conducting membrane is studied. The activation was a repeated pulsed operation of the membrane–electrode assembly (MEA), which was characterized by alternating a constant load of the MEA near a short-circuit current at voltage $U_L$ = 0.1 V and its “idle time” corresponding to the open circuit voltage of the MEA, $U_{\operatorname{OCV}}\approx$ 0.95 V. It is shown that there is an optimal ratio of the time parameters of the pulsed load at which the activation is much more efficient than in the case of constant potentiostatic or galvanostatic regimes often used in practice.

Received: 13.10.2017

DOI: 10.21883/PJTF.2018.13.46325.17078


 English version:
Technical Physics Letters, 2018, 44:7, 570–573

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