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Pisma v Zhurnal Tekhnicheskoi Fiziki, 2024 Volume 50, Issue 24, Pages 84–88 (Mi pjtf6878)

International Conference Physics.SPb/2024

Ilms of 2-methylbenzimidazole perchlorate Ñ$_8$Í$_8$N$_2$–HClO$_4$: phase transformations, crystal structure and dielectric properties

E. V. Balashova, A. A. Levin, B. B. Krichevtsov

Ioffe Institute, St. Petersburg, Russia

Abstract: Films of the semiorganic compound 2-methylbenzimidazole perchlorate, MBI $\cdot$ HClO$_4$, were grown by evaporation at room temperature from an aqueous solution of MBI $\cdot$ HClO$_4$ on quartz glass and sapphire substrates. The results of temperature changes in capacitance, dielectric losses and conductivity of films with simultaneous registration of phase transformations using a polarizing microscope, as well as the results of X-ray diffraction measurements of the crystal structure of MBI $\cdot$ HClO$_4$ films before and after melting and crystallization are presented.

Keywords: phase transformations, crystal structure, dielectric properties, ionic liquids, semi-organic crystals.

Received: 29.04.2024
Revised: 08.07.2024
Accepted: 30.10.2024

DOI: 10.61011/PJTF.2024.24.59447.6466k



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