Abstract:
The electronic structure of a gold film deposited on W was studied during the adsorption of sodium atoms. An analysis of the photoemission spectra from the valence band and core levels of Au 4$f$ and Na 2$p$ upon synchrotron excitation in the photon energy range of 80–600 eV showed that Na adsorption leads to the formation of Na$_x$Au$_y$ intermetallic compounds of various stoichiometry under the Na monolayer.