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Pisma v Zhurnal Tekhnicheskoi Fiziki, 2025 Volume 51, Issue 20, Pages 21–23 (Mi pjtf8362)

$\alpha$-Cr$_2$O$_3$ layers grown on (100) $\beta$-Ga$_2$O$_3$ substrates by ultrasonic vapor chemical epitaxy (mist-CVD)

V. I. Nikolaev, R. B. Timashov, A. I. Stepanov, A. V. Chikiryaka, M. P. Scheglov, S. V. Shapenkov, V. M. Krymov

Ioffe Institute, St. Petersburg

Abstract: Heterocontacts based on $\alpha$-Cr$_2$O$_3$/$\beta$-Ga$_2$O$_3$ have recently aroused interest, as they make it possible to realize the potential of gallium oxide, an ultra-wide-band semiconductor in instrument structures, since the latter has no prospects yet in obtaining p-type conductivity samples with parameters suitable for instrument applications. While for $\alpha$-Cr$_2$O$_3$ it is quite achievable. In this work, for the first time, epitaxial chromium oxide layers on bulk gallium oxide substrates with a thickness of up to 1 micron or more were obtained by the CVD method. The question of the orientation of these layers is investigated. X-ray diffraction revealed that the $\alpha$-Cr$_2$O$_3$ layers grown on (100) $\beta$-Ga$_2$O$_3$ plates have a single layer reflex corresponding to $(11\bar 26)$.

Keywords: gallium oxide, chromium oxide, mist-CVD epitaxy, heterostructures, multilayer films.

Received: 16.06.2025
Revised: 14.07.2025
Accepted: 14.07.2025

DOI: 10.61011/PJTF.2025.20.61396.20406



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© Steklov Math. Inst. of RAS, 2025