Abstract:
Polycrystalline films of magnetite (Fe$_3$O$_4$) formed by the reactive sputtering of iron in oxygen on Si(001) substrates covered by thin (1.4 nm) or thick (1200 nm) SiO$_2$ layers have been studied by Raman spectroscopy. It is established that (i) the $\alpha$-Fe$_2$O$_3$ phase is formed due to the laser-induced heating in magnetite films synthesized on thick SiO$_2$ layers and (ii) the formation of $\alpha$-Fe$_2$O$_3$ phase depends on the thickness of the buffer SiO$_2$ layer.