Kvantovaya Elektronika, 2009 Volume 39, Number 8,Pages 697–704(Mi qe14051)
Active media
Analytic study of the chain dark decomposition reaction of iodides — atomic iodine donors — in the active medium of a pulsed chemical oxygen — iodine laser: 2. Limiting parameters of the branching chain dark decomposition reaction of iodides
Abstract:
The final stages in the development of a branching chain decomposition reaction of iodide in the active medium of a pulsed chemical oxygen — iodine laser (COIL) are analysed. Approximate expressions are derived to calculate the limiting parameters of the chain reaction: the final degree of iodide decomposition, the maximum concentration of excited iodine atoms, the time of its achievement, and concentrations of singlet oxygen and iodide at that moment. The limiting parameters, calculated by using these expressions for a typical composition of the active medium of a pulsed COIL, well coincide with the results of numerical calculations.