Influence of an acceptor on multiphoton dissociation of CF3Br molecules in strong infrared field of a pulsed CO2

A significant increase in the dissociation yield, compared with pure CF₃Br, was achieved when a buffer N₂ and an acceptor NO were added. The frequency dependences of the dissociation yield, absorbed energy, and quantum efficiency of the dissociation of CF₃Br were determined. The isotopic shift was found for the ¹²CF₃Br and ¹³CF₃Br molecules.