N. B. Mikheev, L. N. Auerman, I. A. Rumer, A. N. Kamenskaya, M. Z. Kazakevich, “The anomalous stabilisation of the oxidation state 2+ of lanthanides and actinides”, Usp. Khim., 1992, Volume 61, Issue 10,Pages <nobr>1805

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The anomalous stabilisation of the oxidation state 2+ of lanthanides and actinides

N. B. Mikheev, L. N. Auerman, I. A. Rumer, A. N. Kamenskaya, M. Z. Kazakevich

Institute of Physical Chemistry, Russian Academy of Sciences, Moscow

Abstract: The present review deals with the anomalous stabilisation of the oxidation state 2+ of a number of lanthanides and actinides. This stabilisation of the oxidation state 2+ is due to the lowering of the energy of a d-orbital as a result of crystal field splitting in the ligand field and d-electron participation in chemical bonding.
The bibliography includes 68 references.

UDC: 541.2+546.65+546.66+546.799

Received: 08.05.1992

DOI: 10.1070/RC1992v061n10ABEH001011