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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 2012 Volume 81, Issue 3, Pages 221–238 (Mi rcr11)

This article is cited in 25 papers

The application of green chemistry methods in organophosphorus synthesis

I. L. Odinets, E. V. Matveeva

A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow

Abstract: Data concerning the synthesis of organophosphorus compounds in ionic liquids, in water and under solvent-free conditions are considered and summarized. It is shown that this strategy, which complies with the definition of green chemistry, has advantages in terms of the rate of the process and the yields of target products as compared with syntheses in common organic solvents. The Wittig, Horner–Wadsworth–Emmons, Kabachnik–Fields, Arbuzov and Michaelis reactions are considered as examples. The bibliography includes 178 references.

Received: 01.07.2011

DOI: 10.1070/RC2012v081n03ABEH004248


 English version:
Russian Chemical Reviews, 2012, 81:3, 221–238

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