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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1996 Volume 65, Issue 6, Pages 547–563 (Mi rcr1299)

This article is cited in 36 papers

Cyclic mechanisms of chain termination in the oxidation of organic compounds

E. T. Denisov

Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region

Abstract: All the mechanisms known at present for cyclic (repeated) chain termination involving aromatic amines, quinones, nitroxyl radicals, and variable-valence metal complexes in the oxidation of hydrocarbons, polymers, alcohols, and aliphatic amines are surveyed. The mechanisms are classified and the factors needed for the realisation of a particular mechanism are analysed. The reasons for the limitation of the number of cycles in the cyclic chain termination mechanism are considered. The bibliography includes 84 references.

UDC: 542.943:541.124.7

Received: 10.11.1995

DOI: 10.1070/RC1996v065n06ABEH000302


 English version:
Russian Chemical Reviews, 1996, 65:6, 505–520

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