Thermodynamics of polylactones

The thermodynamic properties of polylactones and the thermodynamic parameters of their formation reactions involving the polymerisation of lactones in the range 0–400 K are examined on the basis of the results of calorimetric studies. The selected thermodynamic quantities which have been recommended for use are presented. The regularities and characteristics of the thermodynamic properties and parameters of the lactone polymerisation reaction and their dependence on the composition, structure and physical state of the reactants and on temperature at the standard pressure are described. The bibliography includes 99 references.