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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1998 Volume 67, Issue 3, Pages 261–273 (Mi rcr1398)

This article is cited in 29 papers

Phase transitions in polymer solutions induced by mechanical fields

S. A. Vshivkova, S. G. Kulichikhinb, E. V. Rusinovaa

a Ural State University, Ekaterinburg
b G. S. Petrov Research Institute of Plastics, Moscow

Abstract: The review summarises and analyses recent results of studies into phase transitions in polymer solutions induced by mechanical fields. Processes of dynamic structure formation preceding phase transitions in shearing and longitudinal fields are described. The effect of molecular weight, chain flexibility, and concentration of the polymer, shear stress (rate), and surface energies of components on the phase separation of polymer solutions in a mechanical field is considered. The theoretical concepts of phase transitions in polymer solutions under mechanical stress are analysed. The bibliography includes 186 references.

UDC: 541.64:532.73:536.7

Received: 29.11.1997

DOI: 10.1070/RC1998v067n03ABEH000319


 English version:
Russian Chemical Reviews, 1998, 67:3, 233–243

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