Abstract:
CONTENTS I. Introduction 347 II. Alkylidenephosphoranes 347 III. Mechanism and stereochemistry of the Wittig reaction 351 IV. Synthesis of natural polyacetylenic compounds 352 V. Synthesis of terpenes, carotenoids, and vitamin A 353 VI. Synthesis of steroids and vitamin D2 357 VII. Prospects for future uses of the Wittig reaction in the synthetic field 358