Abstract:
CONTENTS I. Introduction 455 II. Standardisation of conditions for studying outer-sphere association in aqueous solutions of complex compounds 456 III. Procedure for calculating the outer-sphere association constants for labile complexes 457 IV. The most widely used methods for determining outer-sphere association constants 459 V. Outer-sphere association and the law of mass action 459 VI. Some rules of outer-sphere association 461 VII. Prediction of constants for the association of anionic complexes with alkali metal cations 465 VIII. Comparison of outer-sphere and inner-sphere association constants 465 IX. Complex formation with allowance for associative interaction with the ions of the salt medium 466