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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1968 Volume 37, Issue 1, Pages 167–190 (Mi rcr2147)

This article is cited in 2 papers

Autocatalytic and Impedance Phenomena and the Effect of the Physical State of the Solid Product on the Acceleration and Retardation of Reversible Topochemical Reactions with Participation of Solid and Gaseous Reactants

E. S. Vorontsov

Siberian Metallurgical Institute, Novokuznetsk

Abstract: CONTENTS
I. Introduction 73
II. The mechanism of autocatalysis 74
III. Catalysis by a solid product 78
IV. The impedance phenomenon 80
V. Unblocking of the initial solid phase 81
VI. The Pilling-Bedworth rule and the principle of the acceleration or retardation of reversible topochemical reactions with participation of gaseous and solid reactants 82


DOI: 10.1070/RC1968v037n01ABEH001610


 English version:
Russian Chemical Reviews, 1968, 37:1, 73–85


© Steklov Math. Inst. of RAS, 2024