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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1968 Volume 37, Issue 9, Pages 1547–1566 (Mi rcr2199)

This article is cited in 13 papers

Oxidation of Benzene

E. T. Denisov, D. I. Metelitsa

Chernogolovka Institute of Chemical Physics of the USSR Academy of Sciences

Abstract: The review gives a systematic account of studies on the oxidation of benzene by different methods — with oxygen in the gas phase, with Fenton's reagent in aqueous solution, under the action of light and penetrating radiation, and also catalytic oxidation in aqueous solution. Particular attention has been paid to the mechanism of the oxidation of benzene; the main experimental evidence for individual mechanisms is discussed and unlikely schemes are criticised. Kinetic data and the mechanism of the catalytic oxidation of benzene to phenol with oxygen in aqueous solution in the presence of iron and copper ions which follows from them are discussed in detail. The bibliography incorporates 120 references.

UDC: 547.532:547.563.1

DOI: 10.1070/RC1968v037n09ABEH001690


 English version:
Russian Chemical Reviews, 1968, 37:9, 656–665


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