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Usp. Khim., 1970 Volume 39, Issue 7, Pages 1173–1189 (Mi rcr2370)

Autocondensation of Cyclic Ketones

S. V. Svetozarskii, E. N. Zil'berman


Abstract: The reactions of cyclohexanone and 2-, 3-, and 4-methylcyclohexanones, cyclopentanone, and cycloheptanone, mainly under the action of acid and alkaline reagents, have been examined. The conditions governing the formation and the structures of the dimeric, trimeric, and polymeric autocondensation products – αβ-,βγ-, and other unsaturated ketones, hydroxyketones, compounds with furan or hydrogenated furan rings, dihydropyrans, hydrocarbons such as dodecahydrotriphenylene, and other compounds – have been discussed.
The bibliography includes 102 references.

UDC: 547.284

DOI: 10.1070/RC1970v039n07ABEH002006


 English version:
Russian Chemical Reviews, 1970, 39:7, 553–561

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© Steklov Math. Inst. of RAS, 2024