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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1970 Volume 39, Issue 12, Pages 2154–2186 (Mi rcr2410)

This article is cited in 6 papers

Advances in Asymmetric Hydrogenation. Catalytic Synthesis of Optically Active Hydroxy- and Amino-acids

E. I. Klabunovskii, E. S. Levitina

N. D. Zelinskii Institute of Organic Chemistry of the USSR Academy of Sciences, Moscow

Abstract: In the present review an attempt is made to follow the general relations in the formation of optical isomers and to elucidate the optimum conditions for the reactions on the basis of an analysis of the available literature data on the catalytic synthesis of aminoacids with reference to data on the hydrogenation of C=C and C=O bonds in optically active compounds. The extremely interesting and promising field of asymmetric hydrogenation using dissymmetrical heterogeneous catalysts, which requires special treatment, has been dealt with in the review only in connection with the synthesis of aminoacids.
The bibliography includes 87 references.

UDC: 542.978:547.466

DOI: 10.1070/RC1970v039n12ABEH002325


 English version:
Russian Chemical Reviews, 1970, 39:12, 1035–1049

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© Steklov Math. Inst. of RAS, 2024