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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1973 Volume 42, Issue 2, Pages 273–300 (Mi rcr2602)

This article is cited in 10 papers

Heterophase Radical Polymerisation

V. A. Popov, G. P. Gladyshev

Institute of Chemical Physics of the USSR Academy of Sciences, Moscow

Abstract: The review deals with the characteristics of the heterophase polymerisation of various monomers, the effect of the transition from a homogeneous to a heterogeneous system, and certain physical factors on the rate of polymerisation, the molecular weight of polymers, and the composition of copolymers. A general account is given of published data for the morphological structure of the polymer phase formed. The views of various investigators on the mechanism of the heterophase polymerisation are discussed and the kinetic mechanisms and models of heterophase polymerisation are examined critically.
The bibliography includes 164 references.

UDC: 541.64; 547.15; 547,914,1

DOI: 10.1070/RC1973v042n02ABEH002569


 English version:
Russian Chemical Reviews, 1973, 42:2, 120–135

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