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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1973 Volume 42, Issue 4, Pages 585–614 (Mi rcr2615)

This article is cited in 6 papers

The Use of Proton Magnetic Resonance in the Study of Complexones

N. A. Kostromina

Institute of General and Inorganic Chemistry, Academy of Science of UkrSSR, Kiev

Abstract: The available literature data for the protonation of complexones and the formation of their complexes with diamagnetic and paramagnetic ions are reviewed. A systematic and general account is given of studies on the equilibria and kinetics of complex formation and of the structures of the complexes. Typical PMR spectra of complexones and their metal complexes are presented; quantitative characteristics obtained from PMR data (chemical shifts, spin–spin coupling constants, stability constants, and reaction rate constants) are tabulated.
The bibliography includes 99 references.

UDC: 541.49:547.182.3

DOI: 10.1070/RC1973v042n04ABEH002580


 English version:
Russian Chemical Reviews, 1973, 42:4, 261–277

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