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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1975 Volume 44, Issue 8, Pages 1345–1365 (Mi rcr2814)

This article is cited in 1 paper

Stabilisation of the Surface Potential and Determination of the Activities of Individual Ions in Solution

Yu. F. Rybkin

All-Union Scientific Research Institute for Single Crystals, Scintillation Materials and High Purity Chemicals, Kharkiv

Abstract: The problem of the determination of the thermodynamic characteristics of individual ions, the Galvani potentials, and the liquid junction potentials by a method based on the stabilisation of the surface potentials of electrolyte solutions is examined. The results of experiments on the applications of surface-active agents (aliphatic carboxylic acids, alcohols and amines) as stabilisers of the surface potentials are discussed. The scope and limitations of the method are indicated.
The bibliography includes 85 references.

UDC: 541.13

DOI: 10.1070/RC1975v044n08ABEH002365


 English version:
Russian Chemical Reviews, 1975, 44:8, 625–636

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