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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1976 Volume 45, Issue 1, Pages 71–105 (Mi rcr2860)

This article is cited in 22 papers

The Reactivity of Epithio-compounds

A. V. Fokin, A. F. Kolomiets

A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow

Abstract: The available information about the reactions of epithio-compounds with nucleophilic and electrophilic agents, about the homolytic reactions of alkene sulphides, and about reactions leading to the elimination of sulphur with formation of alkenes is examined, the mechanisms of the opening of thiiran rings are discussed, and the comparative characteristics of the reactivities of O- and S-heteroanalogues of cyclopropane compounds are given.
The bibliography includes 276 references.

UDC: 547.17:547.843

DOI: 10.1070/RC1976v045n01ABEH002590


 English version:
Russian Chemical Reviews, 1976, 45:1, 25–42

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