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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1979 Volume 48, Issue 4, Pages 612–634 (Mi rcr3126)

This article is cited in 14 papers

Catalytic Ionic Hydrogenation

M. I. Kalinkin, G. D. Kolomnikova, Z. N. Parnes, D. N. Kursanov

A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow

Abstract: Data on the catalytic hydrogenation of unsaturated organic compounds in acid media are examined and discussed. A new method of catalytic hydrogenation in acid media, in which the catalyst activates hydrogen and the substrate is activated by the acid which converts it into a positively charged intermediate, is proposed. The role of catalysts as agents transferring hydride ions from molecular hydrogen to carbonium ions is considered.
The bibliography includes 58 references.

UDC: 542.971+542.941

DOI: 10.1070/RC1979v048n04ABEH002330


 English version:
Russian Chemical Reviews, 1979, 48:4, 332–342

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