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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1982 Volume 51, Issue 10, Pages 1638–1673 (Mi rcr3423)

This article is cited in 12 papers

The Unpaired Electron in Transition Metal Complexes

E. R. Milaeva, A. Z. Rubezhov, A. I. Prokof'ev, O. Yu. Okhlobystin

A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow

Abstract: The present state of research into complex and organometallic compounds with an unpaired electron is described. Paramagnetic complexes of transition metals, differing in the position of the free-radical fragment and in the nature of the paramagnetic ligands are examined. The possibility of investigating the intramolecular electron transfer in the metal–ligand system and the formation of intermediate free-radical products in reactions of transition metal compounds is discussed.
The bibliography includes 201 references.

UDC: 547.1'13:547.024

DOI: 10.1070/RC1982v051n10ABEH002933


 English version:
Russian Chemical Reviews, 1982, 51:10, 942–960

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